He founded the Mouratoglou Tennis Academy in 1996 near Paris (later relocated to the outskirts of Nice), and has coached many up-and-coming players, including Marcos Baghdatis (whom he coached to the final of the 2006 Australian Open), Julia Vakulenko, Anastasia Pavlyuchenkova, Aravane Rezaï, Irena Pavlovic, Jérémy Chardy, Laura Robson, Yanina Wickmayer, Grigor Dimitrov and Holger Rune.